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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
05/10/2023 |
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Data da última atualização: |
15/01/2024 |
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Tipo da produção científica: |
Orientação de Tese de Pós-Graduação |
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Autoria: |
CRUZ, J. C. da. |
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Título: |
PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP. |
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Páginas: |
98 p. |
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Idioma: |
Inglês |
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Notas: |
Orientador: Caue Ribeiro de Oliveira
Coorientadora: Elaine Cristina Paris |
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Conteúdo: |
ABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2 MenosABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formatio... Mostrar Tudo |
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Palavras-Chave: |
Superoxidação em CO2. |
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Categoria do assunto: |
-- |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/doc/1157124/1/TS-PHOTOCATALYTIC-CONTROLLED-OXIDATION.pdf
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Marc: |
LEADER 02955nam a2200145 a 4500
001 2157124
005 2024-01-15
008 2023 bl uuuu m 00u1 u #d
100 1 $aCRUZ, J. C. da
245 $aPHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE.$h[electronic resource]
260 $a2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP.$c2023
300 $a98 p.
500 $aOrientador: Caue Ribeiro de Oliveira Coorientadora: Elaine Cristina Paris
520 $aABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2
653 $aSuperoxidação em CO2
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Registro original: |
Embrapa Instrumentação (CNPDIA) |
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Registro Completo
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Biblioteca(s): |
Embrapa Mandioca e Fruticultura. |
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Data corrente: |
08/10/2021 |
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Data da última atualização: |
16/01/2024 |
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Tipo da produção científica: |
Documentos |
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Autoria: |
ROCHA, S. L.; GERUM, A. F. A. de A.; SANTANA, M. do A. |
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Afiliação: |
SANDRO LAMARCA ROCHA; AUREA FABIANA APOLINÁRIO DE ALBUQUERQUE GERUM, CNPMF; MARCELO DO AMARAL SANTANA, CNPMF. |
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Título: |
Canais de comercialização de banana in natura no Brasil. |
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Ano de publicação: |
2021 |
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Fonte/Imprenta: |
Cruz das Almas, BA: Embrapa Mandioca e Fruticultura, 2021. |
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Páginas: |
16p. |
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Descrição Física: |
il. |
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Série: |
(Embrapa Mandioca e Fruticultura. Documentos, 246). |
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ISSN: |
1809- 4996 |
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Idioma: |
Português |
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Conteúdo: |
Apresentação A banana é a fruta mais consumida e produzida no mundo, e a segunda no Brasil. A sua importância na agricultura nacional está bem representada por números: mais de um milhão de pessoas empregadas, cerca de sete milhões de toneladas produzidas e valor da produção de 7,5 bilhões de reais, resultados de árduo trabalho de mais de 200 mil produtores. Embora apresente números grandiosos, os bananicultores brasileiros se deparam com vários desafios na gestão do seu negócio e no acompanhamento da dinâmica do mercado. Este documento apresenta uma visão geral da comercialização de banana no Brasil, enfocando os principais elos e canais da cadeia comercial entre produtores e consumidores, bem como as características de maior relevância para um melhor conhecimento do mercado desta fruteira. A |
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Thesagro: |
Banana; Comercio. |
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Categoria do assunto: |
-- |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/226817/1/Documento246-Aurea-AINFO-1.pdf
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Marc: |
LEADER 01407nam a2200193 a 4500
001 2135177
005 2024-01-16
008 2021 bl uuuu u0uu1 u #d
022 $a1809- 4996
100 1 $aROCHA, S. L.
245 $aCanais de comercialização de banana in natura no Brasil.$h[electronic resource]
260 $aCruz das Almas, BA: Embrapa Mandioca e Fruticultura$c2021
300 $a16p.$cil.
490 $a(Embrapa Mandioca e Fruticultura. Documentos, 246).
520 $aApresentação A banana é a fruta mais consumida e produzida no mundo, e a segunda no Brasil. A sua importância na agricultura nacional está bem representada por números: mais de um milhão de pessoas empregadas, cerca de sete milhões de toneladas produzidas e valor da produção de 7,5 bilhões de reais, resultados de árduo trabalho de mais de 200 mil produtores. Embora apresente números grandiosos, os bananicultores brasileiros se deparam com vários desafios na gestão do seu negócio e no acompanhamento da dinâmica do mercado. Este documento apresenta uma visão geral da comercialização de banana no Brasil, enfocando os principais elos e canais da cadeia comercial entre produtores e consumidores, bem como as características de maior relevância para um melhor conhecimento do mercado desta fruteira. A
650 $aBanana
650 $aComercio
700 1 $aGERUM, A. F. A. de A.
700 1 $aSANTANA, M. do A.
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Embrapa Mandioca e Fruticultura (CNPMF) |
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